| Autor: |
Tate JR; Department of Chemistry, California State University San Bernardino, 5500 University Parkway, San Bernardino, California 92407, USA. jtate@csusb.edu, Kantardjieff K, Crundwell G, Mink LM |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2002 Sep; Vol. 58 (Pt 9), pp. m485-6. Date of Electronic Publication: 2002 Aug 31. |
| DOI: |
10.1107/S0108270102013859 |
| Abstrakt: |
In the title compound, [PtBr(2)(C(48)H(36)N(4)O(4))].0.896CHCl(3).0.569CH(3)CN, the centrosymmetric metal complex is octahedral, with the porphyrin ring essentially planar and the Br atoms occupying axial positions. The two independent methoxyphenyl substituents are tilted at angles of 89.0 and 67.0 degrees with respect to the porphyrin plane. The Pt-N distances are 2.035 (4) and 2.036 (4) A and the Pt-Br distance is 2.4666 (6) A. Chloroform and acetonitrile solvent molecules, exhibiting substantial disorder, occupy positions between the porphyrin molecules. This is the first crystal and molecular structure of a Pt(IV)-porphyrin complex to be reported. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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