Metal ligation regulates conformational equilibria and binding properties of cavitands.
| Autor: | Amrhein P; The Skaggs Institute for Chemical Biology, Scripps Research Institute, MB-26, 10550 North Torrey Pines Rd., La Jolla, CA 92037, USA., Wash PL, Shivanyuk A, Rebek J Jr |
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| Jazyk: | angličtina |
| Zdroj: | Organic letters [Org Lett] 2002 Feb 07; Vol. 4 (3), pp. 319-21. |
| DOI: | 10.1021/ol0167661 |
| Abstrakt: | A self-folding cavitand binds quinuclidinium cation in its vase conformation and lanthanum ions in its kite conformation. Metal coordination provides a novel switching mechanism for the uptake and release of guests. |
| Databáze: | MEDLINE |
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