Autor: |
Helmholdt RB; Laboratory for Crystallography, Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands. rbh@science.uva.nl, Peschar R, Schenk H |
Jazyk: |
angličtina |
Zdroj: |
Acta crystallographica. Section B, Structural science [Acta Crystallogr B] 2002 Feb; Vol. 58 (Pt 1), pp. 134-9. Date of Electronic Publication: 2001 Jan 24. |
DOI: |
10.1107/s0108768101016330 |
Abstrakt: |
The crystal structures of beta-1,2,3-tris(pentadecanoyl)glycerol (beta-C15C15C15), beta-1,2,3-tris(heptadecanoyl)glycerol (beta-C17C17C17) and beta-1,2,3-tris(nonadecanoyl)glycerol (beta-C19C19C19) have been determined from high-resolution X-ray powder diffraction data. Grid search and Rietveld refinement have been used to determine and refine the structures, respectively. As in beta-1,2,3-tris(tridecanoyl)glycerol (beta-C13C13C13) and the even-numbered mono-acid triacylglycerols, all three odd-numbered monoacid triacylglycerols crystallize in space group P1 with Z = 2 in an asymmetric tuning-fork conformation and have a lateral acyl chain packing resulting in a layered structure. |
Databáze: |
MEDLINE |
Externí odkaz: |
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