| Autor: |
Camacho DH; Department of Chemistry, Graduate School of Science and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan., Nakamura I, Saito S, Yamamoto Y |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 2001 Jan 12; Vol. 66 (1), pp. 270-5. |
| DOI: |
10.1021/jo001428j |
| Abstrakt: |
Palladium-catalyzed addition of alcohol pronucleophiles 1 to alkylidenecyclopropane derivatives 2 afforded the corresponding allylic ethers 3 in excellent to moderate yields. Catalyst optimization indicated the Pd(PPh3)4-P(o-tolyl)3 combination as the best system among all catalysts tested. Intramolecular reaction also proceeded smoothly. A plausible mechanism for this catalytic reaction was proposed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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