The occurrence of the herbicide dalapon (2,2-dichloropropionate) in potable water as a disinfection by-productElectronic supplementary information (ESI) available: Fig. SI 1 shows concentrations of haloacetic acids (HAAs) (µg l−1) in treated potable water samples and Table SI 1 shows Spearman’s rank correlation between 2,2-dichloropropionate and HAAs. Fig. SI 2 contains a typical extracted ion chromatogram of 2,2-dichloropropionic acid and Tables SI 2 and 3 detail operating conditions for sample concentrator and autosampler in THM analysis. See DOI: 10.1039/c0em00475h

Autor: Darryl W. Hawker1, Janet L. Cumming2, Andrew Watkinson3, Michael E. Bartkow3
Předmět:
Zdroj: Journal of Environmental Monitoring. Feb2011, Vol. 13 Issue 2, p252-256. 5p.
Abstrakt: Salts of 2,2-dichloropropionic acid, such as dalapon, are well known as herbicides and are regulated as such in potable water in Australia and elsewhere. It is also an identified disinfection by-product (DBP), but little is known about the compound's formation and typical levels from this source. This work presents results from a sampling campaign where 2,2-dichloropropionate was found at levels between 0.1 and 0.5 µg l−1in potable water samples from a major treatment plant in South East Queensland, Australia. However, levels were below the reporting limit (0.01 µg l−1) in the immediate source water for the plant. Also, temporal trends in 2,2-dichloropropionate observed in treated water during sampling mirrored those of trihalomethanes albeit at much lower concentrations, suggesting that the occurrence is due to in situformation as a DBP. This could present a regulatory dilemma in some jurisdictions. [ABSTRACT FROM AUTHOR]
Databáze: GreenFILE