Oxide Contacts in Organic Photovoltaics: Characterization and Control of Near-Surface Composition in Indium−Tin Oxide (ITO) Electrodes.

Autor: Neal R. Armstrong1, P. Alex Veneman1, Erin Ratcliff1, Diogenes Placencia1, Michael Brumbach1
Předmět:
Zdroj: Accounts of Chemical Research. Nov2009, Vol. 42 Issue 11, p1748-1757. 10p.
Abstrakt: The recent improvements in the power conversion efficiencies of organic photovoltaic devices (OPVs) promise to make these technologies increasingly attractive alternatives to more established photovoltaic technologies. OPVs typically consist of photoactive layers 20−100 nm thick sandwiched between both transparent oxide and metallic electrical contacts. Ideal OPVs rely on ohmic top and bottom contacts to harvest photogenerated charges without compromising the power conversion efficiency of the OPV. Unfortunately, the electrical contact materials (metals and metal oxides) and the active organic layers in OPVs are often incompatible and may be poorly optimized for harvesting photogenerated charges. Therefore, further optimization of the chemical and physical stabilities of these metal oxide materials with organic materials will be an essential component of the development of OPV technologies. The energetic and kinetic barriers to charge injection/collection must be minimized to maximize OPV power conversion efficiencies. [ABSTRACT FROM AUTHOR]
Databáze: GreenFILE