| Abstrakt: |
Fouling organisms attach and grow on submerged surfaces causing several economic losses. Thus, biocides have been introduced in antifouling paints in order to avoid this phenomenon, but their widespread use became a global problem, mainly in ports, leisure and fishing boat harbors, since these substances can be highly toxic to non-target organisms. The occurrence and environmental behavior of antifouling biocides are especially unknown in some peculiar regions, such as Amazon areas. Thus, the aim of this work was to evaluate, for the first time, levels and the partitioning behavior of the antifouling organic biocides irgarol, diuron and also stable degradation products of dichlofluanid and diuron (DMSA and DCPMU, respectively) in sediments and porewaters from a high boat traffic area located in the Northeast of Brazil, a pre-Amazon region. Our results showed high concentrations of irgarol (<1.0–89.7 μg kg−1) and diuron (<5.0–55.2 μg kg−1) in sediments. In porewater, DCPMU (<0.03–0.67 μg L−1) and DMSA (<0.008–0.263 μg L−1) were the mainly substances detected. High K d and K oc obtained for both irgarol and diuron showed a partitioning preference in the solid phase. This work represents one of the few registers of contamination by antifouling substances in Amazonian areas, despite their environmental relevance. Image 1 • Sediments and porewaters of Brazilian areas were contaminated by antifouling biocides. • The antifouling contamination was mainly associated to small fishing harbors. • Levels in porewaters accounted for a limited fraction of the contamination. • First occurrence of DMSA related to antifouling use at the Brazilian coast. Sediments and porewaters from Brazilian coast areas are contaminated by antifouling substances. [ABSTRACT FROM AUTHOR] |
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