Development of Novel Bimetallic Catalysts for Nitrene Insertion Reaction

Autor: Po-Hsun Hou, 侯博勳
Rok vydání: 2016
Druh dokumentu: 學位論文 ; thesis
Popis: 104
We successfully synthesized new dirhodium catalyst with bidentate ligand which carries xathene skeleton.For the purpose compare nitrene insertion catelysed bidentate and/or monodentate ligand.We synthesis monodentate catalys Rh2esp(OAc)2 and prove structrue by X-ray successfully. The target of the research is to examine these different catalys in inter- and intra-molecular nitrene insertion to know and compare the effect of different ligand scaffolds.
Databáze: Networked Digital Library of Theses & Dissertations