Di-μ-chlorido-bis{[2-(benzyliminomethyl)pyridine-κ2N,N′]chloridomercury(II)} dichloridomercury(II)
| Autor: | In-Chan Kim, Seong-Jae Yun, Young-Kwang Song, Young-Inn Kim, Sung Kwon Kang |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 1, Pp m52-m53 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810050725 |
| Popis: | The HgII ion in the title centrosymmetric dinuclear complex, [Hg2Cl4(C13H12N2)2]·[HgCl2], adopts a distorted square-pyramidal geometry, being coordinated by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds [2.8428 (11) Å] is significantly longer than the other [2.5327 (10) Å]. In the crystal, there are weak π–π interactions [centroid–centroid distance = 3.630 (3) Å] between the aromatic rings of the discrete units. The HgCl2 adduct molecule is located on an inversion centre and has an Hg—Cl bond length of 2.2875 (11) Å. |
| Databáze: | Directory of Open Access Journals |
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