Telltale diamagnetism at 50 K of a coordination polymer system
| Autor: | Jun He, Xinhe Ye, Zhiqing Liu, Liangming Tang, Jieying Hu, Zhengtao Xu |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Materials Research Letters, Vol 10, Iss 7, Pp 496-500 (2022) |
| Druh dokumentu: | article |
| ISSN: | 21663831 2166-3831 |
| DOI: | 10.1080/21663831.2022.2057822 |
| Popis: | The synthesis of coordination polymers (e.g. Prussian blue) is as old as modern chemistry itself, but never stops surprising people. We here report superconductivity observed of a designer coordination polymer system sporting the chemically soft mercaptan and hard carboxyl groups. The mercapto-carboxyl (dubbed Mercarb, or QiuSuo in Mandarin Pinyin) synergy hints at Daoism and here carries over from the molecular to the solid state: the soft sulfur donors bond with Co2+/Ni2+ (or other transition metal ions) to afford 2D sheets for charge transport, while the interlayer metal-carboxylate domain is more ionic and mediates the transition into the superconductive state. |
| Databáze: | Directory of Open Access Journals |
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