Intrinsic Spectral Resolution Limitations of QEPAS Sensors for Fast and Broad Wavelength Tuning

Autor: Jesper B. Christensen, Lasse Høgstedt, Søren M. M. Friis, Jui-Yu Lai, Ming-Hsien Chou, David Balslev-Harder, Jan C. Petersen, Mikael Lassen
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Sensors, Vol 20, Iss 17, p 4725 (2020)
Druh dokumentu: article
ISSN: 1424-8220
DOI: 10.3390/s20174725
Popis: Quartz-enhanced photoacoustic sensing is a promising method for low-concentration trace-gas monitoring due to the resonant signal enhancement provided by a high-Q quartz tuning fork. However, quartz-enhanced photoacoustic spectroscopy (QEPAS) is associated with a relatively slow acoustic decay, which results in a reduced spectral resolution and signal-to-noise ratio as the wavelength tuning rate is increased. In this work, we investigate the influence of wavelength scan rate on the spectral resolution and signal-to-noise ratio of QEPAS sensors. We demonstrate the acquisition of photoacoustic spectra from 3.1 μm to 3.6 μm using a tunable mid-infrared optical parametric oscillator. The spectra are attained using wavelength scan rates differing by more than two orders of magnitude (from 0.3 nm s−1 to 96 nm s−1). With this variation in scan rate, the spectral resolution is found to change from 2.5 cm−1 to 9 cm−1. The investigated gas samples are methane (in nitrogen) and a gas mixture consisting of methane, water, and ethanol. For the gas mixture, the reduced spectral resolution at fast scan rates significantly complicates the quantification of constituent gas concentrations.
Databáze: Directory of Open Access Journals
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