Removal of benzaldehyde from a water/ethanol mixture by applying scavenging techniques

Autor: Mitic Aleksandar, Skov Thomas, Gernaey Krist V.
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Zdroj: Green Processing and Synthesis, Vol 6, Iss 3, Pp 353-361 (2017)
Druh dokumentu: article
ISSN: 2191-9542
2191-9550
DOI: 10.1515/gps-2016-0085
Popis: A presence of carbonyl compounds is very common in the food industry. The nature of such compounds is to be reactive and thus many products involve aldehydes/ketones in their synthetic routes. By contrast, the high reactivity of carbonyl compounds could also lead to formation of undesired compounds, such as genotoxic impurities. It can therefore be important to remove carbonyl compounds by implementing suitable removal techniques, with the aim of protecting final product quality. This work is focused on benzaldehyde as a model component, studying its removal from a water/ethanol mixture by applying different derivatization agents as the scavengers. Discovery chemistry is performed in the beginning as a screening procedure, followed by the process design of a small-scale continuous process for benzaldehyde removal with in-line real-time monitoring. Applications of tris(hydroxymethyl)aminomethane (TRIS) are found to provide above average removal of benzaldehyde.
Databáze: Directory of Open Access Journals