Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione
| Autor: | Kuppan Chandralekha, Deivasigamani Gavaskar, Adukamparai Rajukrishnan Sureshbabu, Srinivasakannan Lakshmi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 3, Pp 387-390 (2016) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989016002875 |
| Popis: | In the title compound, C36H31NO4, two spiro links connect the methyl-substituted pyrrolidine ring to the acenaphthylene and cyclohexanone rings. The cyclohexanone ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the acenaphthylen-1-one ring system adopts a flattened envelope conformation with the ketonic C atom as flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclohexanone ring assumes a boat conformation. Three intramolecular C—H...O hydrogen bonds involving both ketonic O atoms as acceptors are present. In the crystal, C—H...O hydrogen bonds connect centrosymmetrically related molecule into chains parallel to the b axis, forming rings of R22(10)and R22(8) graph-set motifs. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|