The microstructure and He+ ion irradiation behavior of novel low-activation W-Ta-Cr-V refractory high entropy alloy for nuclear applications

Autor: D. Kalita, I. Jóźwik, Ł. Kurpaska, Y. Zhang, K. Mulewska, W. Chrominski, J. O'Connell, Y. Ge, W.L. Boldman, P.D. Rack, Y. Wang, W.J. Weber, J. Jagielski
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Nuclear Materials and Energy, Vol 37, Iss , Pp 101513- (2023)
Druh dokumentu: article
ISSN: 2352-1791
DOI: 10.1016/j.nme.2023.101513
Popis: Microstructure and nanohardness of a nearly equimolar W-Ta-Cr-V high entropy alloy (HEA), as well as its irradiation response under He+ irradiation, were investigated. The single-phase body-centered cubic nanostructured alloy with a 1 µm thick layer was fabricated on a silicon substrate using a magnetron sputtering method. The HEA film has a complex microstructure consisting of micrometric domains that exhibit internal nanostructure controlled by their crystal orientation. The measured nanohardness of the W-Ta-Cr-V alloy is 13 ± 2 GPa, which significantly exceeds the hardness of nanocrystalline tungsten as a result of the high solid-solution strengthening effect. In order to evaluate the irradiation resistance of the HEA film, the material was irradiated with 200 keV He+ ions at room temperature, with two different ion fluences: 1 × 1016 and 5 × 1016 ions/cm2. Using transmission electron microscopy, a high density of extremely fine He bubbles is observed that were uniformly distributed in the matrix. The increase of He+ ion fluence increased the density of bubbles, whereas their size remained at a similar level, which indicates that the damage proceeds by the nucleation of additional He bubbles, not by their growth.
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