| Autor: |
MILOS B. MILOVANOVIC, SNEZANA S. TRIFUNOVIC, LYNNE KATSIKAS, IVANKA G. POPOVIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2007 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 72, Iss 12, Pp 1507-1514 (2007) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
The free radical copolymerisation of itaconic anhydride and methyl methacrylate in solution was studied at 60 °C. The copolymer composition was determined by 1H-NMR spectroscopy and the obtained monomer reactivity ratios were calculated, rITA = 1.35±0.11; rMMA = 0.22±0.22 (by the Fineman–Ross method) and rITA = 1.27±0.38; rMMA = 0.10±0.05 (by the Mayo–Lewis method). The synthesised copolymers were modified by reaction with di-n-butyl amine. The copolymer composition after amidation was determined by elemental analysis via the nitrogen content. Amidation of the anhydride units in the copolymers with di-n-butyl amine resulted in complete conversion to itaconamic acid. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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