Synthetic routes for N-arylation of carbazole derivatives and their applications as organic materials

Autor: Sobia Mukhtar, Ayesha Rafiq, Syed Ali Raza Naqvi, Sana Aslam, Matloob Ahmad, Sami A. Al-Hussain, Magdi E.A. Zaki
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Saudi Chemical Society, Vol 28, Iss 5, Pp 101927- (2024)
Druh dokumentu: article
ISSN: 1319-6103
DOI: 10.1016/j.jscs.2024.101927
Popis: Carbazole is a heterocyclic aromatic organic compound that has vast applications in pharmaceuticals, and in biological and material sciences. Carbazole derivatives show various biological activities such as antibiotic, anti-inflammatory, anti-tumor and anti-oxidant activities etc. Synthesis of N-arylated carbazoles has become a major area of interest for scientists due to their applications in organic light-emitting diodes, dye-sensitized solar cells, and other organic electronics. The N-arylated carbazoles have unique properties such as high thermal stability, wide band gap, and excellent electrical and optical properties. The methods used for the N-arylation of carbazoles include transition metal-catalyzed reactions and metal-free reactions. The most common and classical methods for the N-arylation of carbazoles are copper-catalyzed Ullmann coupling reactions, while palladium, nickel, and iron catalysts are also used. This review focuses on all the synthetic methods used for the N-arylation of carbazoles and their applications.
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