Autor: |
Xin Fang, Wenhao Zhai, Kun Zhang, Yilun Wang, Li Yao, Cheng Tian, Yi Wan, Ruixiang Hou, Yanping Li, Weixi Chen, Guangzhao Ran |
Jazyk: |
angličtina |
Rok vydání: |
2017 |
Předmět: |
|
Zdroj: |
AIP Advances, Vol 7, Iss 8, Pp 085217-085217-6 (2017) |
Druh dokumentu: |
article |
ISSN: |
2158-3226 |
DOI: |
10.1063/1.4994995 |
Popis: |
Organic-inorganic halide perovskite CH3NH3PbX3 (X= I, Br, Cl) quantum dots (QDs) possess the characters of easy solution-process, high luminescence yield, and unique size-dependent optical properties. In this work, we have improved the nonaqueous emulsion method to synthesize halide perovskite CH3NH3PbBr3 QDs with tunable sizes. Their sizes have been tailored from 5.29 to 2.81 nm in diameter simply by varying the additive amount of surfactant, n-octylamine from 5 to 120 μL. Correspondingly, the photoluminescence (PL) peaks shift markedly from 520 nm to very deep blue, 436 nm due to quantum confinement effect. The PL quantum yields exceed 90% except for the smallest QDs. These high-quality QDs have potential to build high-performance optoelectronic devices. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
|