catena-Poly[[tetraaqua(μ-4,4′-bipyridine-κ2N:N′)zinc(II)] fumarate tetrahydrate]
Autor: | Ji-Wu Wang, Hui Wang, Dong-Sheng Li, Ya-Pan Wu, Yong Tian |
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Jazyk: | angličtina |
Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 5, Pp m662-m663 (2008) |
Druh dokumentu: | article |
ISSN: | 16005368 1600-5368 |
DOI: | 10.1107/S1600536808009227 |
Popis: | In the title compound, {[Zn(C10H8N2)(H2O)4](C4H2O4)·4H2O}n, the ZnII atom is coordinated by two N atoms from two μ-4,4′-bipyridine ligands and four water molecules in a distorted octahedral geometry. The coordination unit is extended through the Zn—N bond, leading to a one-dimensional cationic chain. A twofold rotation axis passes through the Zn atom and along the axis of the 4,4′-bipyridine ligand. Each uncoordinated water molecule acts as both hydrogen-bond donor and acceptor. A three-dimensional network is constructed through hydrogen bonds involving water molecules and fumarate dianions. |
Databáze: | Directory of Open Access Journals |
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