A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges

Autor:	Robert C. Carroll, David C. Harrowven, James E. Pearce, Simon J. Coles
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	crystalline sponge systematic studies metal–organic frameworks single-crystal x-ray diffraction intermolecular interactions mofs Crystallography QD901-999
Zdroj:	IUCrJ, Vol 10, Iss 4, Pp 497-508 (2023)
Druh dokumentu:	article
ISSN:	2052-2525 20522525
DOI:	10.1107/S2052252523005146
Popis:	Utilization of the crystalline sponge {[(ZnI2)3(tpt)2·x(solvent)]n} method has enabled characterization of a novel family of synthetic organic oils. The systematic structural differences and diversity of functional groups offered by 13 related molecular adsorbates provide a detailed quantitative understanding of the relationship between the guest structure, its conformation, and the type of intermolecular interactions adopted with neighbouring guests and the host framework. This analysis is extended to assess the connection of these factors to the resulting quality indicators for a particular molecular structure elucidation.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/ba03bbda60d246eab0f40b1b6615717a Zobrazit plný text záznamu View record in DOAJ