A Tape-Wrapping Strategy towards Electrochemical Fabrication of Water-Dispersible Graphene
| Autor: | Deyue Xiao, Peng He, Haolong Zheng, Shujing Yang, Siwei Yang, Guqiao Ding |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Nanomaterials, Vol 14, Iss 9, p 805 (2024) |
| Druh dokumentu: | article |
| ISSN: | 14090805 2079-4991 |
| DOI: | 10.3390/nano14090805 |
| Popis: | Graphene has achieved mass production via various preparative routes and demonstrated its uniqueness in many application fields for its intrinsically high electron mobility and thermal conductivity. However, graphene faces limitations in assembling macroscopic structures because of its hydrophobic property. Therefore, balancing high crystal quality and good aqueous dispersibility is of great importance in practical applications. Herein, we propose a tape-wrapping strategy to electrochemically fabricate water-dispersible graphene (w-Gr) with both excellent dispersibility (~4.5 mg/mL, stable over 2 months), and well-preserved crystalline structure. A large production rate (4.5 mg/min, six times faster than previous electrochemical methods), high yield (65.4% ≤5 atomic layers) and good processability are demonstrated. A mechanism investigation indicates that the rational design of anode configuration to ensure proper oxidation, deep exfoliation and unobstructed mass transfer is responsible for the high efficiency of this strategy. This simple yet efficient electrochemical method is expected to promote the scalable preparation and applications of graphene. |
| Databáze: | Directory of Open Access Journals |
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