Ultrastable and efficient slight-interlayer-displacement 2D Dion-Jacobson perovskite solar cells

Autor: Weichuan Zhang, Ziyuan Liu, Lizhi Zhang, Hui Wang, Chuanxiu Jiang, Xianxin Wu, Chuanyun Li, Shengli Yue, Rongsheng Yang, Hong Zhang, Jianqi Zhang, Xinfeng Liu, Yuan Zhang, Huiqiong Zhou
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Nature Communications, Vol 15, Iss 1, Pp 1-10 (2024)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-024-50018-4
Popis: Abstract Stability has been a long-standing concern for solution-processed perovskite photovoltaics and their practical applications. However, stable perovskite materials for photovoltaic remain insufficient to date. Here we demonstrate a series of ultrastable Dion−Jacobson (DJ) perovskites (1,4-cyclohexanedimethanammonium)(methylammonium) n−1Pb n I3n+1 (n ≥ 1) for photovoltaic applications. The scalable technology by blade-coated solar cells for the designed DJ perovskites (nominal n = 5) achieves a maximum stabilized power conversion efficiency (PCE) of 19.11% under an environmental atmosphere. Un-encapsulated cells by blade-coated technology retain 92% of their initial efficiencies for over 4000 hours under ~90% relative humidity (RH) aging conditions. More importantly, these cells also exhibit remarkable thermal (85 °C) and operational stability, which shows negligible efficiency loss after exceeding 5000-hour heat treatment or after operation at maximum power point (MPP) exceeding 6000 hours at 45 °C under a 100 mW cm−2 continuous light illumination.
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