Thermoplastic bio-composites from natural Samanea Saman fillers loaded HDPE: Mechanical, thermal, and structural analysis

Autor: C Balaji Ayyanar, K. Marimuthu, S.K. Pradeep Mohan, B. Gayathri, C. Bharathiraj, Resego Phiri, Femiana Gapsari, Putu H. Setyarini, Sanjay Mavinkere Rangappa, Suchart Siengchin
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Results in Engineering, Vol 23, Iss , Pp 102841- (2024)
Druh dokumentu: article
ISSN: 2590-1230
DOI: 10.1016/j.rineng.2024.102841
Popis: This study explores the potential of biodegradable Samanea saman (SS) flower fillers as reinforcements in high-density polyethylene (HDPE) composites, fabricated using injection molding techniques at various filler concentrations. Surface morphology and elemental composition were analyzed using Field Emission Scanning Electron Microscopy (FESEM) and Energy Dispersive X-ray Spectroscopy (EDX), revealing a composition predominantly of Carbon (88.04 %), along with Oxygen, Silicon, Chlorine, Potassium, Calcium, Sodium, and Bromine. The crystal structure of the fillers was identified as orthorhombic via X-ray diffraction (XRD), and the crystallite size was measured at 62.78 nm. Thermal stability assessments conducted through Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) indicated stability up to 210 °C before degradation occurred. Mechanical properties were optimized at a filler content of 40 wt% for Shore D hardness (63.5 ± 0.5 SHN) and compressive strength (25.5 ± 0.5 MPa), and at 30 wt% for tensile (23.5 ± 0.5 MPa) and flexural strength (19.5 ± 0.5 MPa). These results suggest that SS-HDPE composites offer a viable, environmentally friendly alternative for non-load-bearing applications, potentially reducing HDPE usage by up to one-third.
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