Poly[bis(μ3-thiocyanato-κ3N:S:S′)(μ2-thiocyanato-κ2N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)cadmium(II)silver(I)]
| Autor: | Seik Weng Ng, Zhen-Hong Wei, Yu-Yang Li |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 10, Pp m1313-m1314 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681003744X |
| Popis: | The title compound, [AgCd(NCS)3(C22H17N3)]n, is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a μ2-bridging mode and two in a μ3-bridging mode. The ribbon coordination polymer propagates along the a-axis. |
| Databáze: | Directory of Open Access Journals |
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