Preparation of Thiadiazole Modified UiO-68-CdS Composites for RhB Degradation under Visible Light Irradiation

Autor: Lian-Qiang Wei, Jiu-Bin Wei, Fei Yang, Zhi-Wei Li, Hong-Fang Lai
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Crystals, Vol 13, Iss 5, p 785 (2023)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst13050785
Popis: In this paper, the photosensitive Zr-MOF material Thiadiazole-modified UiO-68 (UiO-68N2S) was used to prepare CdS@UiO-68N2S composites by MOF post-reaction. The chemical composition is characterized using PXRD, FT-IR, XPS, SEM, and TGA. Rhodamine B was used as the model dye for photocatalytic degradation to evaluate the performance of CdS@UiO-68N2S under visible light irradiation. Experimental results show that the degradation rate of a 25 mg/L RhB solution (10 mL) reached 94% with 10 mg CdS@UiO-68N2S as a photocatalyst under blue light irradiation in 13 h at room temperature. The mechanism study revealed that O2•− is the reactive oxygen species for the degradation of Rhodamine B. Recycle experiments showed that CdS@UiO-68N2S can be reused for three rounds without a significant reduction of its catalytic function.
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