N-Cyano-7α-methoxycarbonyl-6,14-endo-ethenotetrahydronorthebaine
| Autor: | Mustafa Odabaşoğlu, Serkan Yavuz, Özgür Pamir, Orhan Büyükgüngör, Yılmaz Yıldırır |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 9, Pp o2205-o2206 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 99570394 |
| DOI: | 10.1107/S1600536809032450 |
| Popis: | In the title compound (systematic name: methyl 17-cyano-3,6-dimethoxy-4,5α-epoxy-6,14-endo-ethenomorphinan-7-carboxylate), C23H24N2O5, the dihydrofuran ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclohexene ring adopts an envelope conformation. An intramolecular C—H...O hydrogen bond is observed. Intermolecular C—H...N and C—H...O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|