Syntheses and molecular structures of some di(amidino)monosilanes
| Autor: | Bös Markus, Herbig Marcus, Böhme Uwe, Kroke Edwin |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Main Group Metal Chemistry, Vol 44, Iss 1, Pp 228-238 (2021) |
| Druh dokumentu: | article |
| ISSN: | 0792-1241 2191-0219 |
| DOI: | 10.1515/mgmc-2021-0024 |
| Popis: | The syntheses of three different amidinosilanes of the type Me2Si[N=C(Ph)R]2 with R = pyrrolidino, morpholino, and diethylamino and one derivative with the composition R2Si[N=C(Ph)R]2 with R = morpholino are reported. These compounds were prepared in one-pot syntheses including three consecutive steps. All products are analysed by single crystal X-ray diffraction, NMR, and Raman spectroscopy. The Si–N=C–N units of these compounds show characteristic structural features and cause a significant high field shift of the 29Si NMR signals. |
| Databáze: | Directory of Open Access Journals |
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