| Popis: |
In this study, the amount of phenol adsorbed between 0 and 10 mmol∙L−1 during an immersion calorimetric experiment is compared with the adsorption that takes place once phenol adsorption reaches the solid–solution equilibrium. The activated carbons used were prepared by impregnation of one obtained from coconut shell with solutions of nitric and phosphoric acid, nitric acid with subsequent reflux in ammonium hydroxide solution, and carbonisation in a nitrogen atmosphere at 1073, 1173, and 1273 K. The phenol/activated carbon interactions during the calorimetric experiment and in equilibrium were studied using a modified Langmuir model. The values of the BET surface area for the samples were between 469 and 1113 m2∙g−1, micropore volumes were between 0.18 and 0.43 cm3∙g−1, and the distribution of pore size was between 0.3 and 1.4 nm. The interactions between water and activated carbons determined by immersion enthalpies were between −11.0 and −24.8 J∙g−1, which showed that the treatments modified the surface chemistry of activated carbon. The results show that the presence of nitrogen as a different heteroatom to oxygen on the activated carbon surface favors the phenol adsorption rate, and this process is 97% complete during the calorimetric experiment, indicating that it is an enthalphy-driven processes. |
