Autor: |
Xin Yang, Guoqiang Li, Yue Zhou, Chongzheng Sun, Lei Bi |
Jazyk: |
angličtina |
Rok vydání: |
2024 |
Předmět: |
|
Zdroj: |
Electrochemistry Communications, Vol 161, Iss , Pp 107685- (2024) |
Druh dokumentu: |
article |
ISSN: |
1388-2481 |
DOI: |
10.1016/j.elecom.2024.107685 |
Popis: |
The traditional Pr0.5Sr0.5FeO3 (PSF) cathode is customized with Mn cations to generate the new Pr0.5Sr0.5Fe0.9Mn0.1O3 (PSFMn) cathode for proton-conducting solid oxide fuel cells (H-SOFCs). Compared to the PSF oxide, the new PSFMn has a reduced thermal expansion, making it more compatible with electrolytes. Furthermore, Mn-doping enhances oxygen vacancy production in PSF, as revealed by experimental and first-principle calculations. More crucially, doping Mn into PSF improves proton diffusion kinetics, resulting in quicker proton diffusion and surface exchange. As a result, the H-SOFC with the PSFMn cathode achieves an output of 1446 mW cm−2 at 700 °C, but the PSF cell only achieves fuel cell performance of 1009 mW cm−2. The fundamental cause of the increased cell performance is the significantly reduced polarization resistance, implying that using the Mn-doping strategy enhances the cathode kinetics of conventional PSF cathodes for H-SOFC. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
|