Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2)
| Autor: | Tatiana M. Savankova, Lev G. Akselrud, Lyudmyla I. Ardanova, Alexey V. Ignatov, Eugeni I. Get’man, Roman E. Gladyshevskii, Stanislav N. Loboda |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Journal of Chemistry, Vol 2014 (2014) |
| Druh dokumentu: | article |
| ISSN: | 2090-9063 2090-9071 |
| DOI: | 10.1155/2014/263548 |
| Popis: | Solid solutions of Pb(8−x)Na2Smx(VO4)6O(x/2) were studied using X-ray diffraction analysis including Rietveld refinement and scanning electron microscopy and by measuring their electrical conductivity. Crystal structure of the solid solutions was refined and the solubility region 0≤x≤0.2 was determined for samarium substitution for lead under the scheme 2Pb2++□→2Sm3++O2-. The influence of degree of substitution on the electrical conductivity of solid solutions was established. |
| Databáze: | Directory of Open Access Journals |
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