3He spin-echo scattering indicates hindered diffusion of isolated water molecules on graphene-covered Ir(111)

Autor: Signe Kyrkjebø, Andrew Cassidy, Sam Lambrick, Andrew Jardine, Bodil Holst, Liv Hornekær
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Frontiers in Chemistry, Vol 11 (2023)
Druh dokumentu: article
ISSN: 2296-2646
DOI: 10.3389/fchem.2023.1229546
Popis: The dynamics of water diffusion on carbon surfaces are of interest in fields as diverse as furthering the use of graphene as an industrial-coating technology and understanding the catalytic role of carbon-based dust grains in the interstellar medium. The early stages of water–ice growth and the mobility of water adsorbates are inherently dependent on the microscopic mechanisms that facilitate water diffusion. Here, we use 3He spin-echo quasi-inelastic scattering to probe the microscopic mechanisms responsible for the diffusion of isolated water molecules on graphene-covered and bare Ir(111). The scattering of He atoms provides a non-invasive and highly surface-sensitive means to measure the rate at which absorbates move around on a substrate at very low coverage. Our results provide an approximate upper limit on the diffusion coefficient for water molecules on GrIr(111) of
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