catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]

Autor: Aboubacar Diop, Tidiane Diop, Antoine Blaise Kama, Cheikh Abdou Khadre Diop, Nikolay Tumanov
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: IUCrData, Vol 5, Iss 10, p x201423 (2020)
Druh dokumentu: article
ISSN: 2414-3146
24143146
DOI: 10.1107/S2414314620014236
Popis: The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl2(C3H5NS2)3]n, prepared from CdCl2·H2O and C3H5NS2 (tzdSH) in a 1:3 ratio, are described. The CdII cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl− anions in a distorted octahedral environment. The Cd metal centres are connected via Cl− ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H...Cl hydrogen bonds.
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