catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
Autor: | Aboubacar Diop, Tidiane Diop, Antoine Blaise Kama, Cheikh Abdou Khadre Diop, Nikolay Tumanov |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: | |
Zdroj: | IUCrData, Vol 5, Iss 10, p x201423 (2020) |
Druh dokumentu: | article |
ISSN: | 2414-3146 24143146 |
DOI: | 10.1107/S2414314620014236 |
Popis: | The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl2(C3H5NS2)3]n, prepared from CdCl2·H2O and C3H5NS2 (tzdSH) in a 1:3 ratio, are described. The CdII cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl− anions in a distorted octahedral environment. The Cd metal centres are connected via Cl− ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H...Cl hydrogen bonds. |
Databáze: | Directory of Open Access Journals |
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