Laser-Induced Breakdown Spectroscopy Associated with the Design of Experiments and Machine Learning for Discrimination of Brachiaria brizantha Seed Vigor

Autor: Guilherme Cioccia, Carla Pereira de Morais, Diego Victor Babos, Débora Marcondes Bastos Pereira Milori, Charline Z. Alves, Cícero Cena, Gustavo Nicolodelli, Bruno S. Marangoni
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Sensors, Vol 22, Iss 14, p 5067 (2022)
Druh dokumentu: article
ISSN: 1424-8220
DOI: 10.3390/s22145067
Popis: Laser-induced breakdown spectroscopy (LIBS) associated with machine learning algorithms (ML) was used to evaluate the Brachiaria seed physiological quality by discriminating the high and low vigor seeds. A 23 factorial design was used to optimize the LIBS experimental parameters for spectral analysis. A total of 120 samples from two distinct cultivars of Brachiaria brizantha seeds exhibiting high vigor (HV) and low vigor (LV) in standard tests were studied. The raw LIBS spectra were normalized and submitted to outlier verification, previously to the reduction data dimensionality from principal component analysis. Supervised machine learning algorithm parameters were chosen by leave-one-out cross-validation in the test samples, and it was tested by external validation using a new set of data. The overall accuracy in external validation achieved 100% for HV and LV discrimination, regardless of the cultivar or the classification algorithm.
Databáze: Directory of Open Access Journals
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