Tunable magnetism in titanium-based kagome metals by rare-earth engineering and high pressure

Autor: Long Chen, Ying Zhou, He Zhang, Xuecong Ji, Ke Liao, Yu Ji, Ying Li, Zhongnan Guo, Xi Shen, Richeng Yu, Xiaohui Yu, Hongming Weng, Gang Wang
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Communications Materials, Vol 5, Iss 1, Pp 1-9 (2024)
Druh dokumentu: article
ISSN: 2662-4443
DOI: 10.1038/s43246-024-00513-4
Popis: Abstract Rare-earth engineering is an effective way to introduce and tune magnetism in topological kagome materials, which have been acting as a fertile platform to investigate the quantum interactions between geometry, topology, spin, and correlation. Here, we report the synthesis, structure, and physical properties of titanium-based kagome metals RETi3Bi4 (RE = Yb, Pr, and Nd) with various magnetic states. They all crystallize in the orthogonal space group Fmmm (No. 69), featuring distorted titanium kagome lattices and rare-earth zig-zag chains. By changing the rare earth atoms in the zig-zag chains, the magnetism can be tuned from nonmagnetic YbTi3Bi4 to short-range ordered PrTi3Bi4 (T anomaly ~ 8.2 K), and finally to ferromagnetic NdTi3Bi4 (T c ~ 8.5 K). In-situ resistance measurements of NdTi3Bi4 under high pressure further reveal a tunable ferromagnetic ordering temperature. These results highlight RETi3Bi4 as a promising family of kagome metals to explore nontrivial band topology and exotic phases.
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