The Mechanical Properties of Geopolymers as a Function of Their Shaping and Curing Parameters

Autor: Camille Zoude, Elodie Prud’homme, Kévyn Johannes, Laurent Gremillard
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Ceramics, Vol 7, Iss 3, Pp 873-892 (2024)
Druh dokumentu: article
ISSN: 2571-6131
DOI: 10.3390/ceramics7030057
Popis: This study investigates the impact of curing conditions, porosity and shaping techniques on the mechanical properties of metakaolin-based geopolymers. Geopolymers offer versatility in shaping, including 3D printing, yet the influence of curing conditions after printing on mechanical properties remains unclear. This is assessed by measuring the bending properties of 3D-printed metakaolin-based geopolymer filaments cured under varied humidity and temperature conditions. The influences of porosity and of shaping technique are observed by comparing the compression properties of molded and 3D-printed samples of various porosity. Samples cured at low humidity exhibit unusually high mechanical properties, which decrease when moved from a dry to a humid environment. This behavior may be due to the presence of PEG within the composition and/or to residual stresses due to the too rapid evacuation of water. High humidity is therefore necessary to ensure optimal curing and stable properties. Increasing the curing temperature helps accelerate geopolymerization without significantly compromising mechanical properties. Direct ink writing offers design flexibility and suitable porosity, but the samples appear to exhibit different failure mechanisms than the molded samples. Additional studies are necessary to understand the interactions between PEG and the geopolymer as well as to better identify the fracture mechanisms within the different samples.
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