Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II)

Autor: Di-Chang Zhong, Gui-Quan Guo, Xiao-Hua Zuo, Ji-Hua Deng, Lin Yuan, Rong-Hua Zhu
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 64, Iss 1, Pp m88-m89 (2008)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536807063933
Popis: In the title compound, [Co(C7H5O2)2(C5H6N2)2], the CoII atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by intermolecular N—H...O hydrogen bonds, C—H...π, and π–π stacking interactions involving benzoate anions and 2-aminopyridine molecules.
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