| Autor: |
Jiang-Zhen Qiu, Yong You, Ye Yu, Zhuo-Fan Chen, Cheng-Jie Guo, Yi-Ling Zhong, Wei-Quan Lin, Xu-Gang Shu |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Molecules, Vol 27, Iss 5, p 1571 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
1420-3049 |
| DOI: |
10.3390/molecules27051571 |
| Popis: |
Aiming at constructing photoresponsive spin crossover (SCO) behavior, herein we designed a new ligand Abtz (Abtz = (E)-N-(4-((E)-phenyldiazenyl)phenyl)-1-(thiazol-4-yl)methanimine) which was decorated by a photochromic azobenzene group. Based on this photochromic ligand, a mononuclear Fe(II) SCO molecule [Fe(Abtz)3](BF4)2·(EAC)2 (1, EAC = ethyl acetate) was successfully synthesized and showed a complete one-step SCO behavior. Under continuous UV light and blue-light exposure, the cis–trans photoisomerization of both ligand Abtz and compound 1 in the liquid phase was confirmed through UV–Vis spectra. Moreover, the 1H-NMR spectra of Abtz reveal a trans–cis conversion ratio of 37%. Although the UV–Vis spectra reveal the photochromic behavior for 1 in the solution phase, the SCO behavior in the liquid state is absent according to the variable-temperature Evans method, suggesting the possible decomposition. Moreover, in the solid state, the cis–trans photoisomerization of both Abtz and 1 was not observed, due to the steric hindrance. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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