Importance of interface open circuit potential on aqueous hydrogenolytic reduction of benzyl alcohol over Pd/C

Autor: Guanhua Cheng, Wei Zhang, Andreas Jentys, Erika E. Ember, Oliver Y. Gutiérrez, Yue Liu, Johannes A. Lercher
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nature Communications, Vol 13, Iss 1, Pp 1-8 (2022)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-35554-1
Popis: The open circuit potential (OCP) complicates catalytic reactions significantly. Here the authors demonstrate that the self-established OCP at the catalyst-aqueous interface is important to stabilize the cationic intermediate and transition state, and enhance the reaction rate in benzyl alcohol hydrogenolysis.
Databáze: Directory of Open Access Journals