Synthesis, characterization, thermal

Autor: Selma Bal, Joseph Donald Connolly
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Zdroj: Arabian Journal of Chemistry, Vol 10, Iss 6, Pp 761-768 (2017)
Druh dokumentu: article
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2015.11.012
Popis: This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azo-Schiff base was further reacted with the acetate salts of Copper, Cobalt and Nickel to give three coordination compounds. All synthesized compounds have been characterized through spectral analysis. The coordination compounds have been examined for their thermal and catalytic features. Good and moderate yields were obtained for the oxidation of styrene and cyclohexene. Thermal features of the ligand and its complexes have been explained and the results obtained have supported the proposed structures.
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