(1,2-Dicarba-closo-dodecaboranyl)trimethylmethanaminium iodide
| Autor: | Jong-Dae Lee, Won-Sik Han, Il-Hwan Suh, Sang Ook Kang |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 8, Pp o2148-o2148 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681102928X |
| Popis: | The title compound, [1-(CH3)3NCH2-1,2-C2B10H11]+·I− or C6H22B10N+·I−, was obtained by the reaction of (1,2-dicarba-closo-dodecaboranyl)dimethylmethanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboranyl)tetramethylammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N—Cmethylene—Ccage angle is very large [120.2 (2)°] because of repulsion between the carborane and tetramethylammonium units. In the crystal, ions are linked through C—H...I hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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