BN/Ag hybrid nanomaterials with petal-like surfaces as catalysts and antibacterial agents

Autor: Konstantin L. Firestein, Denis V. Leybo, Alexander E. Steinman, Andrey M. Kovalskii, Andrei T. Matveev, Anton M. Manakhov, Irina V. Sukhorukova, Pavel V. Slukin, Nadezda K. Fursova, Sergey G. Ignatov, Dmitri V. Golberg, Dmitry V. Shtansky
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Beilstein Journal of Nanotechnology, Vol 9, Iss 1, Pp 250-261 (2018)
Druh dokumentu: article
ISSN: 2190-4286
DOI: 10.3762/bjnano.9.27
Popis: BN/Ag hybrid nanomaterials (HNMs) and their possible applications as novel active catalysts and antibacterial agents are investigated. BN/Ag nanoparticle (NP) hybrids were fabricated using two methods: (i) chemical vapour deposition (CVD) of BN NPs in the presence of Ag vapours, and (ii) ultraviolet (UV) decomposition of AgNO3 in a suspension of BN NPs. The hybrid microstructures were studied by high-resolution transmission electron microscopy (HRTEM), high-angular dark field scanning TEM imaging paired with energy dispersion X-ray (EDX) mapping, X-ray photoelectron spectroscopy (XPS), and infrared spectroscopy (FTIR). They were also characterized in terms of thermal stability, Ag+ ion release, catalytic and antibacterial activities. The materials synthesized via UV decomposition of AgNO3 demonstrated a much better catalytic activity in comparison to those prepared using the CVD method. The best catalytic characteristics (100% methanol conversion at 350 °C) were achieved using the UV BN/Ag HNMs without preliminary annealing at 600 °C in an oxidizing atmosphere. Both types of the BN/Ag HNMs possess a profound antibacterial effect against Escherichia coli K-261 bacteria.
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