DENSITY OF STATES FOR AN ELECTRONIC SPECTRUM WITH A FORBIDDEN BAND
Autor: | CASIAN, Anatolie, SANDULEAC, Ionel |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Journal of Engineering Science (Chişinău), Vol XXVII, Iss 3, Pp 33-37 (2020) |
Druh dokumentu: | article |
ISSN: | 2587-3474 2587-3482 |
DOI: | 10.5281/zenodo.3949645 |
Popis: | Quasi-one-dimensional organic crystals with high electrical conductivity at room temperature are prospect materials for thermoelectric applications. However, usually at some low temperature these materials manifest metal-dielectric transition of Peierls type. The aim of this paper is to calculate the density of electronic states and to show that the metal-dielectric transition is determined by the appearance of a forbidden band in the electronic spectrum exactly above the Fermi energy. While decreasing the temperature T, this forbidden band becomes larger and at some T prevails the value of k0T, where k0 is the Boltzmann constant and the carriers cannot be exited across the forbidden band. This temperature corresponds to metal-dielectric transition. |
Databáze: | Directory of Open Access Journals |
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