DENSITY OF STATES FOR AN ELECTRONIC SPECTRUM WITH A FORBIDDEN BAND

Autor: CASIAN, Anatolie, SANDULEAC, Ionel
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Journal of Engineering Science (Chişinău), Vol XXVII, Iss 3, Pp 33-37 (2020)
Druh dokumentu: article
ISSN: 2587-3474
2587-3482
DOI: 10.5281/zenodo.3949645
Popis: Quasi-one-dimensional organic crystals with high electrical conductivity at room temperature are prospect materials for thermoelectric applications. However, usually at some low temperature these materials manifest metal-dielectric transition of Peierls type. The aim of this paper is to calculate the density of electronic states and to show that the metal-dielectric transition is determined by the appearance of a forbidden band in the electronic spectrum exactly above the Fermi energy. While decreasing the temperature T, this forbidden band becomes larger and at some T prevails the value of k0T, where k0 is the Boltzmann constant and the carriers cannot be exited across the forbidden band. This temperature corresponds to metal-dielectric transition.
Databáze: Directory of Open Access Journals