trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ2O,O′)bis(4-methyl-1,2,3-selenadiazole-κN3)copper(II)
| Autor: | Neil M. Boag, Andrew D. Jackson, Paul D. Lickiss, Richard D. Pilkington, Alan D. Redhouse |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 2, Pp m241-m241 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810001297 |
| Popis: | In the title compound, [Cu(C5HF6O2)2(C3H4N2Se)2], the CuII atom (site symmetry overline{1}) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN2O4 octahedral geometry in which the cis angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the pentanedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant intermolecular interactions in the crystal. |
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