ZIF-67-Derived CoSe/NC Composites as Anode Materials for Lithium-Ion Batteries

Autor: Zongyang Li, Lian Ying Zhang, Lei Zhang, Jiamu Huang, Hongdong Liu
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nanoscale Research Letters, Vol 14, Iss 1, Pp 1-11 (2019)
Druh dokumentu: article
ISSN: 1931-7573
1556-276X
DOI: 10.1186/s11671-019-3194-5
Popis: Abstract As a typical metal selenide, CoSe is a kind of foreground anode material for lithium-ion batteries (LIBs) because of its two-dimensional layer structure, good electrical conductivity, and high theoretical capacity. In this work, the original CoSe/N-doped carbon (CoSe/NC) composites were synthesized using ZIF-67 as a precursor, in which the CoSe nanoparticles are encapsulated in NC nanolayers and they are connected through C–Se bonds. The coating structure and strong chemical coupling make the NC nanolayers could better effectively enhance the lithium storage properties of CoSe/NC composites. As a consequence, the CoSe/NC composites deliver a reversible capacity of 310.11 mAh g−1 after 500 cycles at 1.0 A g−1. Besides, the CoSe/NC composites show a distinct incremental behavior of capacity.
Databáze: Directory of Open Access Journals