Crystal structure of the co-crystal fac-triaquatris(thiocyanato-κN)iron(III)–2,3-dimethylpyrazine (1/3)
| Autor: | Olesia I. Kucheriv, Sergii I. Shylin, Tetiana A. Ilina, Sebastian Dechert, Il'ya A. Gural'skiy |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 4, Pp 374-376 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989015004831 |
| Popis: | In the crystal of the title compound, [Fe(NCS)3(H2O)3]·3C6H8N2, the FeIII cation is located on a threefold rotation axis and is coordinated by three N atoms of the thiocyanate anions and three water molecules in a fac arrangement, forming a slightly distorted N3O3 octahedron. Stabilization within the crystal structure is provided by O—H...N hydrogen bonds; the H atoms from coordinating water molecules act as donors to the N atoms of guest 2,3-dimethylpyrazine molecules, leading to a three-dimensional supramolecular framework. |
| Databáze: | Directory of Open Access Journals |
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