Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-ylmethylidene)ethanamine-κ3N,N′,N′′]manganese(II) monohydrate
| Autor: | Daniel Tinguiano, Ibrahima Elhadj Thiam, Moussa Dieng, Mohamed Gaye, Pascal Retailleau |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 10, Pp m1250-m1250 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 98485474 |
| DOI: | 10.1107/S1600536812037877 |
| Popis: | In the title complex, [MnCl2(C13H13N3)]·H2O, the MnII atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-ylmethylidene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O...O distances of 3.103 (7) Å and O...Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing. |
| Databáze: | Directory of Open Access Journals |
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