(Pyridino-15-crown-5-κ5N,O,O′,O′′,O′′′)bis(thiocyanato-κN)manganese(II)
| Autor: | Daqi Wang, Dacheng Li, Zejing Feng, Chengjuan Li |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 4, Pp m557-m557 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053680800679X |
| Popis: | The title complex, [Mn(NCS)2(C13H19NO4)] {systematic name: [3,6,9,12-tetraoxa-18-azabicyclo[12.3.1]octacosa-14(18),15,17-triene-κ5N,O,O′,O′′,O′′′]bis(thiocyanato-κN)manganese(II)}, was obtained by the reaction of MnCl2·4H2O and NaSCN with pyridino-15-crown-5. The Mn2+ center has a distorted pentagonal bipyramidal coordination geometry, coordinated by four O atoms and one N atom of the pyridino-15-crown-5 molecule, and by the N atoms of the two NCS− ligands. |
| Databáze: | Directory of Open Access Journals |
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