Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate

Autor: Yi-Han Tan, Siang-Guan Teoh, Kei-Lin Sek, Wan-Sin Loh, Hoong-Kun Fun
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 5, Pp m595-m596 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810015278
Popis: The asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl·2H2O, contains a complex cation, a chloride anion and two water molecules. The CuII ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O,N-bidentate dl-threoninate ligand and one apical water molecule. In the crystal structure, intermolecular O—H...O, N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the components into layers. A single weak intermolecular C—H...O interaction connects these layers into a three-dimensional network.
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