Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites

Autor: Vukić Nevena, Ristić Ivan S., Marinović-Cincović Milena, Radičević Radmila, Pilić Branka, Cakić Suzana, Budinski-Simendić Jaroslava
Jazyk: English<br />Serbian
Rok vydání: 2019
Předmět:
Zdroj: Hemijska Industrija, Vol 73, Iss 3, Pp 183-196 (2019)
Druh dokumentu: article
ISSN: 0367-598X
2217-7426
DOI: 10.2298/HEMIND190402016V
Popis: This paper presents influence of the type of carbon nanotube functionalization on properties of poly(L-lactide) (PLLA) based nanocomposite materials. For this purpose surface modifications of multi-walled carbon nanotubes (MWCNTs) were performed by chemical and irradiation techniques, while thermo gravimetric analysis, UV-Visible and Fourier-transform infrared (FT-IR) spectroscopies confirmed successful covalent functionalization. Series of PLLA bionanocom-posites with different contents of functionalized MWCNTs (0.7; 1.6; 2.1 wt%), were synthesized via ring-opening solution polymerisation of L-lactide. FT-IR analysis confirmed that grafting of L-lactide, under controlled condition, is possible to perform starting from the surface of functionalized MWCNTs. From differential scanning calorimetry results it was concluded that even low contents of chemically and irradiation functionalized MWCNTs had a significant effect on thermal properties of the prepared nanocomposites, raising the values of melting and glass transition temperatures. Thermogravimetric analysis (TGA) has shown that the degradation onset temperature for composites with chemically functionalized MWCNTs, was much higher than that for the neat poly(L-lactide) sample and composites with irradiation functionalized MWCNTs. Morphology studies by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that poly(L-lactide) covered surfaces and separated functionalized MWCNTs. Good dispersion of carbon nanotubes in polymer matrix enabled conductivity of synthesized materials, as determined by conductivity tests. [Projects of the Serbian Ministry of Education, Science and Technological Development, Grant no. III 45022 and Grant no. III 45020]
Databáze: Directory of Open Access Journals
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