Enhancement of Physical Characteristics of Styrene–Acrylonitrile Nanofiber Membranes Using Various Post-Treatments for Membrane Distillation

Autor: Reza Sallakhniknezhad, Manijeh Khorsi, Ali Sallakh Niknejad, Saeed Bazgir, Ali Kargari, Mohsen Sazegar, Mohsen Rasouli, Soryong Chae
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Membranes, Vol 11, Iss 12, p 969 (2021)
Druh dokumentu: article
ISSN: 2077-0375
DOI: 10.3390/membranes11120969
Popis: Insufficient mechanical strength and wide pore size distribution of nanofibrous membranes are the key hindrances for their concrete applications in membrane distillation. In this work, various post-treatment methods such as dilute solvent welding, vapor welding, and cold-/hot-pressing processes were used to enhance the physical properties of styrene–acrylonitrile (SAN) nanofiber membranes fabricated by the modified electrospinning process. The effects of injection rate of welding solution and a working distance during the welding process with air-assisted spraying on characteristics of SAN nanofiber membranes were investigated. The welding process was made less time-consuming by optimizing system parameters of the electroblowing process to simultaneously exploit residual solvents of fibers and hot solvent vapor to reduce exposure time. As a result, the welded SAN membranes showed considerable enhancement in mechanical robustness and membrane integrity with a negligible reduction in surface hydrophobicity. The hot-pressed SAN membranes obtained the highest mechanical strength and smallest mean pore size. The modified SAN membranes were used for the desalination of synthetic seawater in a direct contact membrane distillation (DCMD). As a result, it was found that the modified SAN membranes performed well (>99.9% removal of salts) for desalination of synthetic seawater (35 g/L NaCl) during 30 h operation without membrane wetting. The cold-/hot-pressing processes were able to improve mechanical strength and boost liquid entry pressure (LEP) of water. In contrast, the welding processes were preferred to increase membrane flexibility and permeation.
Databáze: Directory of Open Access Journals
Nepřihlášeným uživatelům se plný text nezobrazuje