Enhancing Mechanical and Tribological Properties of Epoxy Composites with Ultrasonication Exfoliated MoS2: Impact of Low Filler Loading on Wear Performance and Tribofilm Formation

Autor: Ravisrini Jayasinghe, Maximiano Ramos, Ashveen Nand, Maziar Ramezani
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Nanomaterials, Vol 14, Iss 21, p 1744 (2024)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano14211744
Popis: This study highlights the impact of low amounts of MoS2 quantities on composite performance by examining the effects of ultrasonication exfoliated MoS2 at different loadings (0.1–0.5 wt%) on the mechanical and tribological parameters of epoxy composites. Even at low concentrations, the ultrasonication and exfoliation procedures greatly improve the dispersion of MoS2 in the epoxy matrix, enabling its efficient incorporation into the tribofilm during sliding. Optimum mechanical properties were demonstrated by the MoS2/epoxy composite at 0.3 wt%, including a modulus of elasticity of 0.86 GPa, an ultimate tensile strength of 61.88 MPa, and a hardness of 88.0 Shore D, representing improvements of 61.5%, 35.45%, and 16.21%, respectively. Corresponding tribological tests revealed that high sliding velocity (10 N load, 0.2 m/s) resulted in a 44.07% reduction in the coefficient of friction and an 86.29% reduction in wear rate compared to neat epoxy. The enhanced tribological performance is attributed to the efficient removal and incorporation of MoS2 into the tribofilm, where it acts as a solid lubricant that significantly reduces friction and wear. Even though an ultra-low amount of filler concentration was added to the composite, a unique finding was the high MoS2 content in the tribofilm at higher sliding speeds, enhancing lubrication and wear protection. This study establishes that even ultralow MoS2 content, when uniformly dispersed, can profoundly improve the mechanical and tribological properties of epoxy composites, offering a novel approach to enhancing wear resistance.
Databáze: Directory of Open Access Journals